With a reinterpretation of recent results, the GRACE Follow-On mission can be applied to gravitational wave astronomy. Existing GRACE Follow-On data constrain the stochastic gravitational wave background to $\Omega_{GW}<3.3\times10^{7}$ at 100 mHz. With a dedicated analysis, GRACE Follow-On may be able to detect the inspiral of local neutron star binaries, inspiral of subgalactic stellar-mass black hole binaries, or mergers of intermediate-mass black hole binaries within the Milky Way.