Measuring the spectral properties of an optical frequency comb is among the most fundamental tasks of precision metrology. In contrast to general single-parameter measurement schemes, we demonstrate here single shot multiparameter estimation at and beyond the standard quantum limit. The mean energy and the central frequency of ultrafast pulses are simultaneously determined with a multi-pixel-spectrally-resolved (MPSR) apparatus, without changing the photonics architecture. Moreover, using a quantum frequency comb that consists of multiple squeezed states in a family of Hermite-Gaussian spectral/temporal modes, the signal-to-noise ratios of the mean energy and the central frequency measurements surpass the shot-noise limit by around 19% and 15%, respectively. Combining our multi-pixel detection scheme and the intrinsic multimode quantum resource could find applications in ultrafast quantum metrology and multimode quantum information processing.
