Nanosized Monoatomic Palladium Metallic Glass

التفاصيل البيبلوغرافية
العنوان: Nanosized Monoatomic Palladium Metallic Glass
المؤلفون: He, Dong Sheng, Huang, Yi, Myers, Benjamin D., Isheim, Dieter, Fan, Xinyu, Deng, Yunsheng, Xie, Lin, Han, Shaobo, Qiu, Yang, Huang, Li, Dravid, Vinayak P., He, Jiaqing
سنة النشر: 2020
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Physically vitrifying single-element metallic glass requires ultrahigh cooling rates, which are still unachievable for most of the closest-packed metals. Here, we report a facile synthetic strategy for creating mono-atomic palladium metallic glass nanoparticles with a purity of 99.35 +/- 0.23 at% from palladium-silicon liquid droplets using a cooling rate below 1000 K/s. In-situ environmental transmission electron microscopy directly detected the leaching of silicon. Further hydrogen absorption experiment showed that this palladium metallic glass expanded little upon hydrogen uptake, exhibiting a great potential application for hydrogen separation. Our results provide insight into the formation of mono-atomic metallic glass at nanoscale.
Comment: Nano Res. (2022)
نوع الوثيقة: Working Paper
DOI: 10.1007/s12274-022-4173-1
URL الوصول: http://arxiv.org/abs/2004.01851
رقم الأكسشن: edsarx.2004.01851
قاعدة البيانات: arXiv
الوصف
DOI:10.1007/s12274-022-4173-1