Investigating resonant low-energy electron attachment to formamide: dynamics of model peptide bond dissociation and other fragmentation channels

التفاصيل البيبلوغرافية
العنوان: Investigating resonant low-energy electron attachment to formamide: dynamics of model peptide bond dissociation and other fragmentation channels
المؤلفون: Panelli, Guglielmo, Moradmand, Ali, Griffin, Brandon, Swanson, Kyle, Weber, Thorsten, Rescigno, Thomas N., McCurdy, C. William, Slaughter, Daniel S., Williams, Joshua B.
المصدر: Phys. Rev. Research 3, 013082 (2021)
سنة النشر: 2020
المجموعة: Physics (Other)
مصطلحات موضوعية: Physics - Chemical Physics, Physics - Atomic Physics
الوصف: We report experimental results on three-dimensional momentum imaging measurements of anions generated via dissociative electron attachment to gaseous formamide. From the momentum images, we analyze the angular and kinetic energy distributions for NH$_2^{-}$, O$^{-}$, and H$^{-}$ fragments and discuss the possible electron attachment and dissociation mechanisms for multiple resonances for two ranges of incident electron energies, from 5.3~eV to 6.8~eV, and from 10.0~eV to 11.5~eV. {\it Ab initio} theoretical results for the angular distributions of the NH$_2^{-}$ anion for $\sim$6~eV incident electrons, when compared with the experimental results, strongly suggest that one of the two resonances producing this fragment is a $^2$A$''$ Feshbach resonance.
Comment: 10 pages, 6 figures
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevResearch.3.013082
URL الوصول: http://arxiv.org/abs/2011.13438
رقم الأكسشن: edsarx.2011.13438
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevResearch.3.013082