Fluctuation profiles in inhomogeneous fluids

التفاصيل البيبلوغرافية
العنوان: Fluctuation profiles in inhomogeneous fluids
المؤلفون: Eckert, Tobias, Stuhlmüller, Nico C. X., Sammüller, Florian, Schmidt, Matthias
المصدر: Phys. Rev. Lett. 125, 268004, (2020)
سنة النشر: 2020
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Soft Condensed Matter, Condensed Matter - Statistical Mechanics
الوصف: Three one-body profiles that correspond to local fluctuations in energy, in entropy, and in particle number are used to describe the equilibrium properties of inhomogeneous classical many-body systems. Local fluctuations are obtained from thermodynamic differentiation of the density profile or equivalently from average microscopic covariances. The fluctuation profiles follow from functional generators and they satisfy Ornstein-Zernike relations. Computer simulations reveal markedly different fluctuations in confined fluids with Lennard-Jones, hard sphere, and Gaussian core interactions.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevLett.125.268004
URL الوصول: http://arxiv.org/abs/2012.05594
رقم الأكسشن: edsarx.2012.05594
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevLett.125.268004