PbMnTeO6: a chiral quasi 2D magnet with all cations in octahedral coordination and the space group problem of trigonal layered A2+Mn4+TeO6

التفاصيل البيبلوغرافية
العنوان: PbMnTeO6: a chiral quasi 2D magnet with all cations in octahedral coordination and the space group problem of trigonal layered A2+Mn4+TeO6
المؤلفون: Kuchugura, Mariia D., Kurbakov, Alexander I., Zvereva, Elena A., Vasilchikova, Tatyana M., Raganyan, Grigory V., Vasiliev, Alexander N., Barchuk, Victor A., Nalbandyan, Vladimir B.
سنة النشر: 2021
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Antiferromagnetic PbMnTeO6, also known as mineral kuranakhite, has been reported recently to have all three cations in trigonal prismatic coordination, which is extremely unusual for both Mn(4+) and Te(6+). In this work, the phase was reproduced with the same lattice parameters and N\'eel temperature TN = 20 K. However, powder neutron diffraction unambiguously determined octahedral (trigonal antiprismatic) coordination for all cations within the chiral space group P312. The same symmetry was proposed for SrMnTeO6 and PbGeTeO6, instead of the reported space groups P-62m and P31m, respectively. PbMnTeO6 was found to be a robust antiferromagnet with an assumingly substantial scale of exchange interactions since the Neel temperature did not show any changes in external magnetic fields up to 7 T. The determined effective magnetic moment meff = 3.78 mB was in excellent agreement with the numerical estimation using the effective g-factor g = 1.95 directly measured here by electron spin resonance (ESR). Both specific heat and ESR data indicated the two-dimensional character of magnetism in the compound under study. The combination of chirality with magnetic order makes PbMnTeO6 a promising material with possible multiferroic properties.
نوع الوثيقة: Working Paper
DOI: 10.1039/C9DT03154E
URL الوصول: http://arxiv.org/abs/2101.10669
رقم الأكسشن: edsarx.2101.10669
قاعدة البيانات: arXiv