Nano-sheets of two-dimensional polymers with dinuclear (arene)ruthenium nodes, synthesised at a liquid/liquid interface

التفاصيل البيبلوغرافية
العنوان: Nano-sheets of two-dimensional polymers with dinuclear (arene)ruthenium nodes, synthesised at a liquid/liquid interface
المؤلفون: Herrero, Ana Cristina Gómez, Féron, Michel, Bendiab, Nedjma, Hertog, Martien Den, Reita, Valérie, Salut, Roland, Palmino, Frank, Coraux, Johann, Chérioux, Frédéric
المصدر: Nanotechnology 32, 355603 (2021)
سنة النشر: 2021
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: We developed a new class of mono- or few-layered two-dimensional polymers based on dinuclear (arene)ruthenium nodes, obtained by combining the imine condensation with an interfacial chemistry process, and use a modified Langmuir-Schaefer method to transfer them onto solid surfaces. Robust nano-sheets of 2D polymers including dinuclear complexes of heavy ruthenium atoms as nodes were synthesised. These nano-sheets, whose thickness is of a few tens of nanometers, were suspended onto solid porous membranes. Then, they were thoroughly characterised with a combination of local probes, including Raman scattering, Fourier transform infrared spectroscopy and transmission electron microscopy in imaging and diffraction mode.
Comment: 9 pages, 2 schemes, 4 figures
نوع الوثيقة: Working Paper
DOI: 10.1088/1361-6528/ac0472
URL الوصول: http://arxiv.org/abs/2106.05534
رقم الأكسشن: edsarx.2106.05534
قاعدة البيانات: arXiv
الوصف
DOI:10.1088/1361-6528/ac0472