Spatial correlations of entangled polymer dynamics

التفاصيل البيبلوغرافية
العنوان: Spatial correlations of entangled polymer dynamics
المؤلفون: Ma, Jihong, Carrillo, Jan-Michael Y., Do, Changwoo, Chen, Wei-Ren, Falus, Péter, Shen, Zhiqiang, Hong, Kunlun, Sumpter, Bobby G., Wang, Yangyang
المصدر: Phys. Rev. E 104, 024503 (2021)
سنة النشر: 2021
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Soft Condensed Matter
الوصف: The spatial correlations of entangled polymer dynamics are examined by molecular dynamics simulations and neutron spin-echo spectroscopy. Due to the soft nature of topological constraints, the initial spatial decays of intermediate scattering functions of entangled chains are, to the first approximation, surprisingly similar to those of an unentangled system in the functional forms. However, entanglements reveal themselves as a long tail in the reciprocal-space correlations, implying a weak but persistent dynamic localization in real space. Comparison with a number of existing theoretical models of entangled polymers suggests that they cannot fully describe the spatial correlations revealed by simulations and experiments. In particular, the strict one-dimensional diffusion idea of the original tube model is shown to be flawed. The dynamic spatial correlation analysis demonstrated in this work provides a useful tool for interrogating the dynamics of entangled polymers. Lastly, the failure of the investigated models to even qualitatively predict the spatial correlations of collective single-chain density fluctuations points to a possible critical role of incompressibility in polymer melt dynamics.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevE.104.024503
URL الوصول: http://arxiv.org/abs/2108.00964
رقم الأكسشن: edsarx.2108.00964
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevE.104.024503