Direct observation of Jahn-Teller critical dynamics at a charge-order Verwey transition

التفاصيل البيبلوغرافية
العنوان: Direct observation of Jahn-Teller critical dynamics at a charge-order Verwey transition
المؤلفون: Gastaldo, Vinícius Pascotto, Rao, Mala N., Bosak, Alexey, d'Astuto, Matteo, Prodi, Andrea, Verseils, Marine, Klein, Yannick, Bellin, Christophe, Paolasini, Luigi, de Oliveira, Adilson J. A., Gilioli, Edmondo, Chaplot, Samrath Lal, Gauzzi, Andrea
المصدر: Phys. Rev. B 104, 235114 (2021)
سنة النشر: 2021
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Strongly Correlated Electrons
الوصف: By means of diffuse and inelastic x-ray scattering (DS,IXS), we probe directly the charge-ordering (CO) dynamics in the Verwey system (NaMn$_3$)Mn$_4$O$_{12}$, where a peculiar quadruple perovskite structure with no oxygen disorder stabilizes a nearly full Mn$^{3+}$/Mn$^{4+}$ static charge order at $T_{\rm CO}$=175 K concomitant to a commensurate structural modulation with propagation vector ${\bf q}_{\rm CO}=(\frac{1}{2},\frac{1}{2},0)$. At $T_{\rm CO}$, the IXS spectra unveil a softening of a 35.3 meV phonon at ${\bf q}_{\rm CO}$. Lattice dynamical calculations enable us to attribute this soft phonon to a A$_g$ mode whose polarization matches the Jahn-Teller-like distortion pattern of the structural modulation. This result demonstrates that the Jahn-Teller instability is the driving force of the CO Verwey transition in (NaMn$_3$)Mn$_4$O$_{12}$, thus elucidating a long-standing controversy regarding the mechanism of this transition observed in other mixed-valence systems like magnetite.
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.104.235114
URL الوصول: http://arxiv.org/abs/2112.04485
رقم الأكسشن: edsarx.2112.04485
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevB.104.235114