Ferroelectric transition of a chiral molecular crystal BINOL2DMSO

التفاصيل البيبلوغرافية
العنوان: Ferroelectric transition of a chiral molecular crystal BINOL2DMSO
المؤلفون: Nomura, Toshihiro, Yajima, Takeshi, Yang, Zhuo, Kurihara, Ryosuke, Ishii, Yuto, Tokunaga, Masashi, Matsuda, Yasuhiro H., Kohama, Yoshimitsu, Kimura, Kenta, Kimura, Tsuyoshi
المصدر: J. Phys. Soc. Jpn. 91, 064702 (2022)
سنة النشر: 2022
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: We report dielectric, thermodynamical, acoustic, and optical properties of a chiral molecular crystal, 1,1'-bi-2-naphthol 2-dimethylsulfoxide (BINOL2DMSO). We find two successive phase transitions at Tc1=190 K and Tc2=125 K. The first transition at Tc1 is characterized by an order-disorder transition of the guest molecules DMSO along with ferroelectricity. At the second transition of Tc2, the crystal structure deforms from tetragonal to monoclinic, leading to domain formation. Low-temperature x-ray diffraction suggests that the space group changes from P4_12_12 (P4_32_12) to P4_1 (P4_3) at Tc1, and down to P112_1 at Tc2.
Comment: 16 pages, 10 figures
نوع الوثيقة: Working Paper
DOI: 10.7566/JPSJ.91.064702
URL الوصول: http://arxiv.org/abs/2204.01241
رقم الأكسشن: edsarx.2204.01241
قاعدة البيانات: arXiv