Charge transfer dynamics in MoSe$_{2}$/hBN/WSe$_{2}$ heterostructures

التفاصيل البيبلوغرافية
العنوان: Charge transfer dynamics in MoSe$_{2}$/hBN/WSe$_{2}$ heterostructures
المؤلفون: Yoon, Yoseob, Zhang, Zuocheng, Qi, Ruishi, Joe, Andrew Y., Sailus, Renee, Watanabe, Kenji, Taniguchi, Takashi, Tongay, Sefaattin, Wang, Feng
المصدر: Nano Lett. 22, 10140 (2022)
سنة النشر: 2022
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Mesoscale and Nanoscale Physics
الوصف: Ultrafast charge transfer processes provide a facile way to create interlayer excitons in directly contacted transition metal dichalcogenide (TMD) layers. More sophisticated heterostructures composed of TMD/hBN/TMD enable new ways to control interlayer exciton properties and achieve novel exciton phenomena, such as exciton insulators and condensates, where longer lifetimes are desired. In this work, we experimentally study the charge transfer dynamics in a heterostructure composed of a 1 nm thick hBN spacer between MoSe$_{2}$ and WSe$_{2}$ monolayers. We observe the hole transfer from MoSe$_{2}$ to WSe$_{2}$ through the hBN barrier with a time constant of 500 ps, which is over 3 orders of magnitude slower than that between TMD layers without a spacer. Furthermore, we observe strong competition between the interlayer charge transfer and intralayer exciton-exciton annihilation processes at high excitation densities. Our work opens possibilities to understand charge transfer pathways in TMD/hBN/TMD heterostructures for the efficient generation and control of interlayer excitons.
نوع الوثيقة: Working Paper
DOI: 10.1021/acs.nanolett.2c04030
URL الوصول: http://arxiv.org/abs/2209.14521
رقم الأكسشن: edsarx.2209.14521
قاعدة البيانات: arXiv
الوصف
DOI:10.1021/acs.nanolett.2c04030