Synthesis of technetium hydride TcH$_{1.3}$ at 27 GPa

التفاصيل البيبلوغرافية
العنوان: Synthesis of technetium hydride TcH$_{1.3}$ at 27 GPa
المؤلفون: Zhou, D., Semenok, D. V., Volkov, M. A., Troyan, I. A., Seregin, A. Yu., Chepkasov, I. V., Sannikov, D. A., Lagoudakis, P. G., Oganov, A. R., German, K. E.
المصدر: Physical Review B, 004100 (2023)
سنة النشر: 2022
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science, Condensed Matter - Superconductivity
الوصف: In this work, we synthesize and investigate lower technetium hydrides at pressures up to 45 GPa using the synchrotron X-ray diffraction, reflectance spectroscopy, and ab initio calculations. In the Tc-H system, the hydrogen content in TcH$_x$ phases increases when the pressure rises, and at 27 GPa we found a new hexagonal (hcp) nonstoichiometric hydride TcH$_{1.3}$. The formation of technetium hydrides is also confirmed by the emergence of a new reflective band at 450-600 nm in the reflectance spectra of TcH$_x$ samples synthesized at 45 GPa. On the basis of the theoretical analysis, we proposed crystal structures for the TcH$_{0.45 \pm 0.05}$ (Tc$_{16}$H$_7$) and TcH$_{0.75 \pm 0.05}$ (Tc$_4$H$_3$) phases previously obtained at 1-2 GPa. The calculations of the electron-phonon interaction show that technetium hydrides TcH$_{1+x}$ do not possess superconducting properties due to the low electron-phonon interaction parameter ($\lambda \sim 0.23$).
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevB.107.064102
URL الوصول: http://arxiv.org/abs/2210.01518
رقم الأكسشن: edsarx.2210.01518
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevB.107.064102