Revisiting the antiferromagnetic structure of $\rm Tb_{14}Ag_{51}$. The importance of distinguishing alternative symmetries for a multidimensional order parameter

التفاصيل البيبلوغرافية
العنوان: Revisiting the antiferromagnetic structure of $\rm Tb_{14}Ag_{51}$. The importance of distinguishing alternative symmetries for a multidimensional order parameter
المؤلفون: Pomjakushin, V., Perez-Mato, J. M., Fischer, P., Keller, L., Sikora, W.
المصدر: Acta Cryst. (2022). B78, 172-178
سنة النشر: 2023
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Strongly Correlated Electrons, Condensed Matter - Other Condensed Matter
الوصف: We revisit the antiferromagnetic structure of $\rm Tb_{14}Ag_{51}$ [P. Fischer., $et\, al$. (2005). PRB, 72 134413] with the propagation vector $[{1\over3},{1\over3},{0}] $ and parent space group $P6/m$ using both magnetic symmetry and irreducible representation arguments. We have found a new magnetic structure under the hexagonal Shubnikov magnetic space group $P\bar{6}'$, which fits much better the experimental data. This new solution was obtained by constraining the spin arrangement to one of the three possible magnetic space groups of maximal symmetry that can be realised by a magnetic ordering transforming according to the 4-dimensional physically irreducible representation that is known to be relevant in this magnetic phase. The refined model, parameterised under $P\bar{6}'$, implicitly includes the presence of a third harmonic with the propagation vector at the gamma point $[0,0,0]$, which has an important weight in the final result. The structure consists of 13 symmetry-independent Tb magnetic moments with the same size of $8.48(2)\mu_B$, propagating cycloidally in the $ab$-plane. The modulation has a substantial deviation from being purely sinusoidal due to the contribution of the mentioned third harmonic.
Comment: 4 pages, 1 table, 7 figures
نوع الوثيقة: Working Paper
DOI: 10.1107/S205252062200124X
URL الوصول: http://arxiv.org/abs/2301.06920
رقم الأكسشن: edsarx.2301.06920
قاعدة البيانات: arXiv
الوصف
DOI:10.1107/S205252062200124X