Effect of sample height and particle elongation in the sedimentation of colloidal rods

التفاصيل البيبلوغرافية
العنوان: Effect of sample height and particle elongation in the sedimentation of colloidal rods
المؤلفون: Eckert, Tobias, Schmidt, Matthias, Heras, Daniel de las
المصدر: Soft Matter 2023
سنة النشر: 2023
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Soft Condensed Matter, Condensed Matter - Materials Science
الوصف: We study theoretically the effect of a gravitational field on the equilibrium behaviour of a colloidal suspension of rods with different length-to-width aspect ratios. The bulk phases of the system are described with analytical equations of state. The gravitational field is then incorporated via sedimentation path theory, which assumes a local equilibrium condition at each altitude of the sample. The bulk phenomenology is significantly enriched by the presence of the gravitational field. In a suspension of elongated rods with five stable phases in bulk, the gravitational field stabilizes up to fifteen different stacking sequences. The sample height has a non-trivial effect on the stable stacking sequence. New layers of distinct bulk phases appear either at the top, at the bottom, or simultaneously at the top and the bottom when increasing the sample height at constant colloidal concentration. We also study sedimentation in a mass-polydisperse suspension in which all rods have the same shape but different buoyant masses.
نوع الوثيقة: Working Paper
DOI: 10.1039/D3SM00191A
URL الوصول: http://arxiv.org/abs/2302.08790
رقم الأكسشن: edsarx.2302.08790
قاعدة البيانات: arXiv