تقرير
Dispersion of Multiferroic Nanoparticles in a Bent-Core Nematic Liquid Crystal: Experimental and Theoretical Study
العنوان: | Dispersion of Multiferroic Nanoparticles in a Bent-Core Nematic Liquid Crystal: Experimental and Theoretical Study |
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المؤلفون: | Mandal, Dhananjoy, Wang, Yiwei, Kaur, Supreet, Mohiuddin, Golam, Majumdar, Apala, Sinha, Aloka |
سنة النشر: | 2023 |
المجموعة: | Condensed Matter |
مصطلحات موضوعية: | Condensed Matter - Soft Condensed Matter |
الوصف: | A novel nanocomposite system has been prepared by dispersing multiferroic bismuth ferrite nanoparticles (BiFeO$_3$) in a bent-core nematic liquid crystal (8-F-OH) that exhibits cybotactic clusters. Transition temperature, optical textures, order parameter $S_m$, and dielectric spectroscopy experiments are performed in the doped system, and the results are compared with the pure one. The main experimental outcome is that the doped system has increased orientational order parameters, even though the cybotactic cluster size is reduced due to the incorporation of multiferroic BiFeO$_3$ nanoparticles. The transition temperature, as observed under polarising optical microscopy, clearly indicates a reduction of $1 - 2~ ^\circ{\rm C}$ in the doped system compared to the pure one, and we conjecture this is due to the disordering of the cybotactic cluster in the doped system. Based on the experimental findings, a Landau-de Gennes-type free energy model is developed. The model qualitatively explains the increased mean order parameter and the disordering of cybotactic clusters with increasing polarization value of nanoparticles. This is corroborated by experimental findings. Comment: 16 pages, 27 figures |
نوع الوثيقة: | Working Paper |
URL الوصول: | http://arxiv.org/abs/2306.14623 |
رقم الأكسشن: | edsarx.2306.14623 |
قاعدة البيانات: | arXiv |
الوصف غير متاح. |