The optical absorption in indirect semiconductor to semimetal PtSe2 arises from direct transitions

التفاصيل البيبلوغرافية
العنوان: The optical absorption in indirect semiconductor to semimetal PtSe2 arises from direct transitions
المؤلفون: Tharrault, Marin, Ayari, Sabrine, Desgué, Eva, Arfaoui, Mehdi, Goff, Romaric Le, Morfin, Pascal, Palomo, José, Rosticher, Michael, Jaziri, Sihem, Plaçais, Bernard, Legagneux, Pierre, Carosella, Francesca, Voisin, Christophe, Ferreira, Robson, Baudin, Emmanuel
سنة النشر: 2023
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science, Condensed Matter - Mesoscale and Nanoscale Physics
الوصف: $\rm{PtSe_2}$ is a van der Waals material transiting from an indirect semiconductor to a semimetal with increasing thickness. Its absorption threshold has been conjectured to originate from interband indirect transitions. By quantitative comparison between wideband optical absorption ($0.8 - 3.0\,\rm{eV}$) of high-quality exfoliated crystals and ab-initio simulations, we prove instead that the optical absorption arises only from direct transitions. This understanding allows us to shed new light on the semiconductor to semimetal transition and to explore the effect of stacking and excitons on optical absorption.
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/2311.01847
رقم الأكسشن: edsarx.2311.01847
قاعدة البيانات: arXiv