Strain fluctuations unlock ferroelectricity in wurtzites

التفاصيل البيبلوغرافية
العنوان: Strain fluctuations unlock ferroelectricity in wurtzites
المؤلفون: Baksa, Steven M., Gelin, Simon, Oturak, Seda, Spurling, Robert Jackson, Sepehrinezhad, Alireza, Jacques, Leonard, Trolier-McKinstry, Susan E., van Duin, Adri C. T., Maria, Jon-Paul, Rappe, Andrew M., Dabo, Ismaila
سنة النشر: 2023
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Ferroelectrics are of practical interest for non-volatile data storage due to their reorientable, crystallographically defined polarization. Yet efforts to integrate conventional ferroelectrics into ultrathin memories have been frustrated by film-thickness limitations, which impede polarization reversal under low applied voltage. Wurtzite materials, including magnesium-substituted zinc oxide (Zn,Mg)O, have been shown to exhibit scalable ferroelectricity as thin films. In this work, we explain the origins of ferroelectricity in (Zn,Mg)O, showing that large strain fluctuations emerge locally in (Zn,Mg)O and can reduce local barriers to ferroelectric switching by more than 40%. We provide concurrent experimental and computational evidence of these effects by demonstrating polarization switching in ZnO/(Zn,Mg)O/ZnO heterostructures featuring built-in interfacial strain gradients. These results open up an avenue to develop scalable ferroelectrics by controlling strain fluctuations atomistically.
Comment: 12 pages, 5 figures
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/2311.05413
رقم الأكسشن: edsarx.2311.05413
قاعدة البيانات: arXiv