Discovery of thiofulminic acid with the QUIJOTE line survey: A study of the isomers of HNCS and HNCO in TMC-1

التفاصيل البيبلوغرافية
العنوان: Discovery of thiofulminic acid with the QUIJOTE line survey: A study of the isomers of HNCS and HNCO in TMC-1
المؤلفون: Cernicharo, José, Agúndez, Marcelino, Cabezas, Carlos, Tercero, Belén, Fuentetaja, Raúl, Marcelino, Nuria, de Vicente, Pablo
سنة النشر: 2024
المجموعة: Astrophysics
مصطلحات موضوعية: Astrophysics - Astrophysics of Galaxies
الوصف: We present the first detection of HCNS (thiofulminic acid) in space with the QUIJOTE line survey in the direction of TMC-1. We performed a complete study of the isomers of CHNS and CHNO, including NCO and NCS. The derived column densities for HCNS, HNCS, and HSCN are (9.0+/-0.5)e9, (3.2+/-0.1)e11, and (8.3+/-0.4)e11 cm-2, respectively. The HNCS/HSCN abundance ratio is 0.38. The abundance ratios HNCO/HNCS, HCNO/HCNS, HOCN/HSCN, and NCO/NCS are 34+/-4, 8.3+/-0.7, 0.18+/-0.03, and 0.78+/-0.07, respectively. These ratios cannot be correctly reproduced by our gas-phase chemical models, which suggests that formation paths for these species are missing, and/or that the adopted dissociative recombination rates for their protonated precursors have to be revised. The isotopologues H15NCO, DNCO, N13CO, DCNO, H34SCN, and DSCN have also been detected with the ultrasensitive QUIJOTE line survey.
Comment: Accepted as a Letter in Astronomy & Astrophysics on 09 January 2024
نوع الوثيقة: Working Paper
DOI: 10.1051/0004-6361/202349105
URL الوصول: http://arxiv.org/abs/2401.11785
رقم الأكسشن: edsarx.2401.11785
قاعدة البيانات: arXiv
الوصف
DOI:10.1051/0004-6361/202349105