The science program of the Radio Neutrino Observatory-Greenland (RNO-G) extends beyond particle astrophysics to include radioglaciology and, as we show herein, solar physics, as well. Impulsive solar flare observations not only permit direct measurements of light curves, spectral content, and polarization on time scales significantly shorter than most extant dedicated solar observatories, but also offer an extremely useful above-surface calibration source, with pointing precision of order tens of arc-minutes. Using the early RNO-G data from 2022-2023, observed flare characteristics are compared to well-established solar observatories. Also, a number of individual flares are used to highlight angular reconstruction and calibration methods. RNO-G observes signal excesses during solar flares reported by the solar-observing Callisto network and in coincidence with about 60% of the brightest excesses recorded by the SWAVES satellite, when the Sun is above the horizon for RNO-G. In these observed flares, there is significant impulsivity in the time-domain. In addition, the solar flares are used to calibrate the RNO-G absolute pointing on the radio signal arrival direction to sub-degree resolution.
