In this paper, we study the fractal properties of the boundary of the Cantorval connected with Guthrie-Nymann's series. In particular, we prove that such a Cantorval can be represented as a union of open intervals and a Cantor set having zero Lebesgue measure and a fractional Hausdorff dimension. Moreover, we extend the result to a countable family of Cantorvals with a similar structure.