Iterative composition optimization in Fe$_2$VAl-based thin-film thermoelectrics using single-target sputtering

التفاصيل البيبلوغرافية
العنوان: Iterative composition optimization in Fe$_2$VAl-based thin-film thermoelectrics using single-target sputtering
المؤلفون: Riss, Alexander, Lasisch, Ellena, Podbelsek, Simon, Schäfer, Katharina, Parzer, Michael, Garmroudi, Fabian, Eisenmenger-Sittner, Christoph, Mori, Takao, Bauer, Ernst
سنة النشر: 2024
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Magnetron sputtering inherently exhibits the advantage of dislodging particles from the target in a ratio equivalent to the target stoichiometry. Nevertheless, film compositions often deviate due to element-dependent scattering with the working gas, necessitating the adjustment of the sputtering process. In this work, we explore an unconventional approach of addressing this issue, involving the employment of an off-stoichiometric target. The required composition is obtained through an iterative process, which is demonstrated by Fe$_2$VAl and Fe$_2$V$_{0.9}$Ti$_{0.1}$Al films as case studies. Ultimately, the correct stoichiometry is obtained from Fe$_{1.86}$V$_{1.15}$Al$_{0.99}$ and Fe$_{1.88}$V$_{1.02}$Ti$_{0.13}$Al$_{0.97}$ targets, respectively. Despite the thermoelectric properties falling below expectations, mainly due to imperfect film crystallization, the strategy successfully achieved the desired stoichiometry, enabling accurate film synthesis without the need of advanced sputtering setups.
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/2406.04729
رقم الأكسشن: edsarx.2406.04729
قاعدة البيانات: arXiv