Kinetic theory of diffusion in a channel of varying cross section

التفاصيل البيبلوغرافية
العنوان: Kinetic theory of diffusion in a channel of varying cross section
المؤلفون: Brey, J. Javier, de Soria, M. I. García, Maynar, P.
سنة النشر: 2024
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Statistical Mechanics
الوصف: Self-diffusion along the longitudinal coordinate in a channel of varying cross section is considered. The starting point is the two-dimensional Enskog-Boltzmann-Lorentz kinetic equation with appropriated boundary conditions. It is integrated over the transversal coordinate to get an approximated one-dimensional kinetic equation, keeping the relevant properties of the original one. Then, a macroscopic equation for the time evolution of the longitudinal density is derived, by means of a modified Chapman-Enskog expansion method, that takes into account the inhomogeneity of the equilibrium longitudinal density. This transport equation has the form of the phenomenological Ficks-Jacobs equation, but with an effective diffusion coefficient that contains corrections associated to the variation of the slope of the equilibrium longitudinal density profile.
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/2407.04300
رقم الأكسشن: edsarx.2407.04300
قاعدة البيانات: arXiv