دورية أكاديمية
Gallium and germanium static and kinetic sorption and desorption studies on cerium dioxide nanoparticles
| العنوان: | Gallium and germanium static and kinetic sorption and desorption studies on cerium dioxide nanoparticles |
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| المؤلفون: | Kateřina Ondrák Fialová, Kryštof Adámek, Karel Štamberg, Ferdinand Šebesta, Martin Vlk, Ján Kozempel |
| المصدر: | SN Applied Sciences, Vol 5, Iss 12, Pp 1-10 (2023) |
| بيانات النشر: | Springer, 2023. |
| سنة النشر: | 2023 |
| المجموعة: | LCC:Science LCC:Technology |
| مصطلحات موضوعية: | Cerium dioxide, Desorption, Ge/Ga separation, Kinetic models, Nanoparticles, Sorption, Science, Technology |
| الوصف: | Abstract Positron-emitting 68Ga has become an integral part of nuclear medicine. It is a radionuclide obtained from 68Ge/68Ga radionuclide generators. Apart from other qualities, it is a feature that have caused its growing popularity in medical practice. Nevertheless, the increasing demand for 68Ga supply results in the need of new and improved separation systems to obtain it. Hydrous oxides such as titanium or zirconium dioxide are usually the preferred separation materials, but other oxidic materials are under study. Thorough testing of the sorption behaviour is often overlooked in these studies, though it is indispensable for the applicability and suitability assessment. This work is focused on the sorption behaviour description of cerium dioxide prepared by calcination of ceric nitrate. Both batch and kinetic sorption experiments were conducted. Such a thorough study has never been carried out for this material. In batch experiments, the optimal conditions for separation of 68Ga and 68Ge were found. Kinetic experimental data were used for mathematical modelling. Six kinetic models derived from various rate-controlling processes were used and their applicability was demonstrated. The diffusion in an inert layer is the rate-controlling process of both gallium and germanium sorption and desorption. This model description of sorption kinetics will further enable us to optimise the sorption and desorption processes numerically. Thus far, it was found out that the prepared cerium dioxide can quantitatively adsorb germanium in very short time of 10 min from 1mM hydrochloric acid and the most convenient medium for 68Ge and 68Ga separation is 0.1 M hydrochloric acid. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2523-3963 2523-3971 |
| Relation: | https://doaj.org/toc/2523-3963; https://doaj.org/toc/2523-3971 |
| DOI: | 10.1007/s42452-023-05561-y |
| URL الوصول: | https://doaj.org/article/024701e6c19546e38a19f0855113609f |
| رقم الأكسشن: | edsdoj.024701e6c19546e38a19f0855113609f |
| قاعدة البيانات: | Directory of Open Access Journals |
Find this article in full text from Springer Verlag. 
Full Text Finder | تدمد: | 25233963 25233971 |
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| DOI: | 10.1007/s42452-023-05561-y |