دورية أكاديمية
Deactivation of a Vanadium-Based SCR Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation
| العنوان: | Deactivation of a Vanadium-Based SCR Catalyst Used in a Biogas-Powered Euro VI Heavy-Duty Engine Installation |
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| المؤلفون: | Johanna Englund, Sandra Dahlin, Andreas Schaefer, Kunpeng Xie, Lennart Andersson, Soran Shwan, Per-Anders Carlsson, Lars J. Pettersson, Magnus Skoglundh |
| المصدر: | Catalysts, Vol 10, Iss 5, p 552 (2020) |
| بيانات النشر: | MDPI AG, 2020. |
| سنة النشر: | 2020 |
| المجموعة: | LCC:Chemical technology LCC:Chemistry |
| مصطلحات موضوعية: | NH3-SCR, V2O5-WO3/TiO2, catalyst deactivation, biogas, methane, engine-bench, Chemical technology, TP1-1185, Chemistry, QD1-999 |
| الوصف: | We have investigated how the exhaust gases from a heavy-duty Euro VI engine, powered with biogas impact a vanadium-based selective catalytic reduction (SCR) catalyst in terms of performance. A full Euro VI emission control system was used and the accumulation of catalyst poisons from the combustion was investigated for the up-stream particulate filter as well as the SCR catalyst. The NOx reduction performance in terms of standard, fast and NO2-rich SCR was evaluated before and after exposure to exhaust from a biogas-powered engine for 900 h. The SCR catalyst retains a significant part of its activity towards NOx reduction after exposure to biogas exhaust, likely due to capture of catalyst poisons on the up-stream components where the deactivation of the oxidation catalyst is especially profound. At lower temperatures some deactivation of the first part of the SCR catalyst was observed which could be explained by a considerably higher surface V4+/V5+ ratio for this sample compared to the other samples. The higher value indicates that the reoxidation of V4+ to V5+ is partially hindered, blocking the redox cycle for parts of the active sites. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2073-4344 |
| Relation: | https://www.mdpi.com/2073-4344/10/5/552; https://doaj.org/toc/2073-4344 |
| DOI: | 10.3390/catal10050552 |
| URL الوصول: | https://doaj.org/article/07a4ba5502d345edbb543f87b6fe38b0 |
| رقم الأكسشن: | edsdoj.07a4ba5502d345edbb543f87b6fe38b0 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20734344 |
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| DOI: | 10.3390/catal10050552 |