دورية أكاديمية

Influence of Chemical Treatments Sequence on Morphology and Crystallinity of Sorghum Fibers

التفاصيل البيبلوغرافية
العنوان: Influence of Chemical Treatments Sequence on Morphology and Crystallinity of Sorghum Fibers
المؤلفون: Ismojo Ismojo, Abdul Aziz Ammar, Ghiska Ramahdita, Anne Zulfia, Mochamad Chalid
المصدر: Indonesian Journal of Chemistry, Vol 18, Iss 2, Pp 349-353 (2018)
بيانات النشر: Department of Chemistry, Universitas Gadjah Mada, 2018.
سنة النشر: 2018
المجموعة: LCC:Chemistry
مصطلحات موضوعية: microfibrillated cellulose (MFC), sorghum bagasse, chemical treatments, crystallinity index, FE-SEM, FTIR, Chemistry, QD1-999
الوصف: Micro-fibrillated cellulose (MFC) derived from natural fibre is continuously gaining interest to produce an environmentally-friendly material, due to economic and ecological reasons. In consequence, sorghum is one of the most-cultivated crops that usually remain the waste as by product of bioethanol production. Indeed, it will be a promising area to utilize sorghum waste to produce MFC for enhancing polymer performance, especially in terms of crystallinity. The objective of this study is to investigate the effect of a sequence of chemical modification was applied to sorghum fibres, i.e. alkalization using 4% sodium hydroxide followed by bleaching using 1.7% sodium chlorite plus acetic acid as a buffer. The treatment was purposed to unbundle the lignocellulose networks into microfibrils cellulose with less amorphous part and lower hydrophilic properties. Evaluation of the chemical treatments effect on internal microstructure, crystallinity index and chemical composition of sorghum fibre was measured via Field-Emission Scanning Electron microscope (FE-SEM), X-ray Diffraction (XRD) and Fourier Transformation Infra-Red (FTIR) Spectroscopy. The experiments show that treatments led to a removal of binding materials, such as amorphous parts hemicellulose and lignin, from the sorghum fibres, resulting MFC of sorghum fibres and enhanced crystallinity index from 41.12 % to 75.73%.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 1411-9420
2460-1578
Relation: https://jurnal.ugm.ac.id/ijc/article/view/27194; https://doaj.org/toc/1411-9420; https://doaj.org/toc/2460-1578
DOI: 10.22146/ijc.27194
URL الوصول: https://doaj.org/article/0972979f2e6148c9a5b3d9dba4a75629
رقم الأكسشن: edsdoj.0972979f2e6148c9a5b3d9dba4a75629
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:14119420
24601578
DOI:10.22146/ijc.27194