دورية أكاديمية
Tetramethylammonium (Z)-N′-cyanocarbamimidate
| العنوان: | Tetramethylammonium (Z)-N′-cyanocarbamimidate |
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| المؤلفون: | Ray J. Butcher, Andrew P. Purdy |
| المصدر: | IUCrData, Vol 6, Iss 11, p x211098 (2021) |
| بيانات النشر: | International Union of Crystallography, 2021. |
| سنة النشر: | 2021 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | crystal structure, cyanourea salt, tetramethylammonium salt, Crystallography, QD901-999 |
| الوصف: | In the structure of the tetramethyl ammonium salt of cyanourea, C4H12N+·C2H2N3O−, the N—C and O—C bond distances in the cyano and keto groups are in the normal range for such a moieties at 1.1641 (18) and 1.2550 (16) Å. However, the bonds about the central C and N atoms are much shorter than would be expected for single bonds and indicate that there is considerable electron delocalization in the anion as was also found in the silver salt. The NH2 group is coplanar with the central N2CO core, in contrast with the nitrile group where the dihedral angle between the N—C—N and N2CO planes is 36.5 (3)°. The packing of the cations and anions in the unit cell involves N—H...O hydrogen bonds between anions characterized by an R22(8) motif, as well as N—H...O hydrogen bonds between anions and C—H...O interactions between both cations and anions, forming an R33(14) pattern. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2414-3146 24143146 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S2414314621010981; https://doaj.org/toc/2414-3146 |
| DOI: | 10.1107/S2414314621010981 |
| URL الوصول: | https://doaj.org/article/a0a07eb19d9a449a9bedb15b68acb3d5 |
| رقم الأكسشن: | edsdoj.0a07eb19d9a449a9bedb15b68acb3d5 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 24143146 |
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| DOI: | 10.1107/S2414314621010981 |