دورية أكاديمية

Portable SA/CMC entrapped bimetallic magnetic fly ash zeolite spheres for heavy metals contaminated industrial effluents treatment via batch and column studies

التفاصيل البيبلوغرافية
العنوان: Portable SA/CMC entrapped bimetallic magnetic fly ash zeolite spheres for heavy metals contaminated industrial effluents treatment via batch and column studies
المؤلفون: Ganesh Kumar Reddy Angaru, Yu-Lim Choi, Lakshmi Prasanna Lingamdinne, Janardhan Reddy Koduru, Jae-Kyu Yang, Yoon-Young Chang, Rama Rao Karri
المصدر: Scientific Reports, Vol 12, Iss 1, Pp 1-17 (2022)
بيانات النشر: Nature Portfolio, 2022.
سنة النشر: 2022
المجموعة: LCC:Medicine
LCC:Science
مصطلحات موضوعية: Medicine, Science
الوصف: Abstract Heavy metals are perceived as a significant environmental concern because of their toxic effect, bioaccumulation, and persistence. In this work, a novel sodium alginate (SA) and carboxymethylcellulose (CMC) entrapped with fly ash derived zeolite stabilized nano zero-valent iron and nickel (ZFN) (SA/CMC-ZFN), followed by crosslinking with CaCl2, is synthesized and applied for remediation of Cu(II) and Cr(VI) from industrial effluent. The characterization of the adsorbent and its surface mechanism for removing metals were investigated using advanced instrumental techniques, including XRD, FT-IR, SEM–EDX, BET, and XPS. The outcomes from the batch experiments indicated that monolayer adsorption on homogeneous surfaces (Langmuir isotherm model) was the rate-limiting step in both heavy metals sorption processes. The maximum adsorption capacity of as-prepared SA/CMC-ZFN was 63.29 and 10.15 mg/g for Cu(II) and Cr(VI), respectively. Owing to the fact that the wastewater released from industries are large and continuous, a continuous column is installed for simultaneous removal of heavy metal ions from real industrial wastewater. The outcomes revealed the potential of SA/CMC-ZFN as an efficient adsorbent. The experimental breakthrough curves fitted well with the theoretical values of Thomas and Yoon-Nelson models. Overall, the results indicated that SA/CMC-ZFN is a viable, efficient, and cost-effective water treatment both interms of batch and column processes.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2045-2322
Relation: https://doaj.org/toc/2045-2322
DOI: 10.1038/s41598-022-07274-5
URL الوصول: https://doaj.org/article/0bf93b65db944b17ab326fe0b603a1e6
رقم الأكسشن: edsdoj.0bf93b65db944b17ab326fe0b603a1e6
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:20452322
DOI:10.1038/s41598-022-07274-5