Lithology identification is the basis for sweet spot evaluation, prediction, and precise exploratory deployment and has important guiding significance for areas with low exploration degrees. The lithology of the shale strata, which are composed of fine-grained sediments, is complex and varies regularly in the vertical direction. Identifying complex lithology is a typical nonlinear classification problem, and intelligent algorithms can effectively solve this problem, but different algorithms have advantages and disadvantages. Compared were the three typical algorithms of Fisher discriminant analysis, BP neural network, and classification and regression decision tree (C&RT) on the identification of seven lithologies of shale strata in the lower 1st member of the Shahejie Formation (Es1L) of Raoyang sag. Fisher discriminant analysis method is linear discriminant, the recognition effect is poor, the accuracy is 52.4%; the accuracy of the BP neural network to identify lithology is 82.3%, but it belongs to the black box and can not be visualized; C&RT can accurately identify the complex lithology of Es1L, the accuracy of this method is 85.7%, and it can effectively identify the interlayer and thin interlayer in shale strata.