دورية أكاديمية
A Water-Soluble Leggero Pillar[5]arene
العنوان: | A Water-Soluble Leggero Pillar[5]arene |
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المؤلفون: | Jia-Rui Wu, Gengxin Wu, Zhi Cai, Dongxia Li, Meng-Hao Li, Yan Wang, Ying-Wei Yang |
المصدر: | Molecules, Vol 27, Iss 19, p 6259 (2022) |
بيانات النشر: | MDPI AG, 2022. |
سنة النشر: | 2022 |
المجموعة: | LCC:Organic chemistry |
مصطلحات موضوعية: | leggero pillar[5]arene, host–guest systems, pillararene, molecular recognition, Organic chemistry, QD241-441 |
الوصف: | The study of aqueous-phase molecular recognition of artificial receptors is one of the frontiers in supramolecular chemistry since most biochemical processes and reactions take place in an aqueous medium and heavily rely on it. In this work, a water-soluble version of leggero pillar[5]arene bearing eight positively charged pyridinium moieties (CWP[5]L) was designed and synthesized, which exhibited good binding affinities with certain aliphatic sulfonate species in aqueous solutions. Significantly, control experiments demonstrate that the guest binding performance of CWP[5]L is superior to its counterpart water-soluble macrocyclic receptor in traditional pillararenes. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 27196259 1420-3049 |
Relation: | https://www.mdpi.com/1420-3049/27/19/6259; https://doaj.org/toc/1420-3049 |
DOI: | 10.3390/molecules27196259 |
URL الوصول: | https://doaj.org/article/12fb53598cbd46abb161ad85260fbb36 |
رقم الأكسشن: | edsdoj.12fb53598cbd46abb161ad85260fbb36 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 27196259 14203049 |
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DOI: | 10.3390/molecules27196259 |