دورية أكاديمية
Structure of the five-coordinate CoII complex (1H-imidazole){tris[(1-benzyltriazol-4-yl-κN3)methyl]amine-κN}cobalt(II) bis(tetrafluoroborate)
العنوان: | Structure of the five-coordinate CoII complex (1H-imidazole){tris[(1-benzyltriazol-4-yl-κN3)methyl]amine-κN}cobalt(II) bis(tetrafluoroborate) |
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المؤلفون: | Vipul Batra, Garrett C. Reed, David L. Tierney |
المصدر: | Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 5, Pp 486-488 (2024) |
بيانات النشر: | International Union of Crystallography, 2024. |
سنة النشر: | 2024 |
المجموعة: | LCC:Crystallography |
مصطلحات موضوعية: | cobalt(ii), five-coordinate, tbta, imidazole, crystal structure, Crystallography, QD901-999 |
الوصف: | The title compound, [Co(C3H4N2)(C30H30N10)](BF4)2, is a five-coordinate CoII complex based on the neutral ligands tris[(1-benzyltriazol-4-yl)methyl]amine (tbta) and imidazole. It exhibits a distorted trigonal bipyramidal geometry in which the equatorial positions are occupied by the three N-atom donors from the triazole rings of the tripodal tbta ligand. The apical amine N-atom donor of tbta and the N-atom donor of the imidazole ligand occupy the axial positions of the coordination sphere. Two tetrafluoroborate anions provide charge balance in the crystal. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2056-9890 20569890 04798821 |
Relation: | http://scripts.iucr.org/cgi-bin/paper?S205698902400330X; https://doaj.org/toc/2056-9890 |
DOI: | 10.1107/S205698902400330X |
URL الوصول: | https://doaj.org/article/177607c802a047988211538d87728749 |
رقم الأكسشن: | edsdoj.177607c802a047988211538d87728749 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 20569890 04798821 |
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DOI: | 10.1107/S205698902400330X |