دورية أكاديمية
أعرض في EDS

Development of unsupported IrO2 nano-catalysts for polymer electrolyte membrane water electrolyser applications

التفاصيل البيبلوغرافية
العنوان: Development of unsupported IrO2 nano-catalysts for polymer electrolyte membrane water electrolyser applications
المؤلفون: Simoné Karels, Cecil Felix, Sivakumar Pasupathi
المصدر: South African Journal of Science, Vol 120, Iss 3/4 (2024)
بيانات النشر: Academy of Science of South Africa, 2024.
سنة النشر: 2024
المجموعة: LCC:Science
LCC:Science (General)
LCC:Social Sciences
LCC:Social sciences (General)
مصطلحات موضوعية: iridium oxide, oxygen evolution reaction, modified Adams fusion method, polymer electrolyte membrane water electrolyser, molten salt method, Science, Science (General), Q1-390, Social Sciences, Social sciences (General), H1-99
الوصف: IrO2 is a current state-of-the-art catalyst for polymer electrolyte membrane water electrolyser (PEMWE) applications due to its high stability during the oxygen evolution reaction (OER). However, its activity needs to be significantly improved to justify the use of such a high-cost material. In this study, the activity of the IrO2 catalyst was improved by optimising and comparing two synthesis methods: the modified Adams fusion method (MAFM) and the molten salt method (MSM). Optimum OER performances of the IrO2 catalysts synthesised with the two synthesis methods were obtained at different temperatures. For the MAFM, a synthesis temperature of 350 °C produced the IrO2 catalyst with an overpotential of 279 mV and the highest OER stability of ~ 82 h at 10 mAcm−2. However, for the MSM, the lowest overpotential of 271 mV was observed for IrO2 synthesised at 350 °C, while the highest stability of ~ 75 h was obtained for the IrO2 synthesised at 500 °C. Significance: IrO2 is still currently a state-of-the-art catalyst in PEMWE due to its high stability in the highly acidic and oxidising conditions of the OER. High-performance IrO2 catalysts were successfully produced via the MAFM and MSM. Both the MAFM and MSM are simple and easily scalable for high-volume production of metal oxide catalysts. This study showed that the physical/structural properties of the IrO2 catalysts can be tailored through synthesis methods and synthesis conditions to improve their OER performance.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 1996-7489
Relation: https://sajs.co.za/article/view/16026; https://doaj.org/toc/1996-7489
DOI: 10.17159/sajs.2024/16026
URL الوصول: https://doaj.org/article/1b325734aa69446594b9953289e8da25
رقم الأكسشن: edsdoj.1b325734aa69446594b9953289e8da25
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:19967489
DOI:10.17159/sajs.2024/16026