The effect of coupling of copper and phosphorus in steel on atmospheric corrosion behavior was investigated using high-throughput experimental methods. Wire beam electrodes and plates with discrete distribution of composition gradients were prepared through a selective laser melting method. By combining array electrode scanning tests and EPMA, the electrochemical properties and the relationship between different copper and phosphorus contents were rapidly determined. Plenty of data obtained were analyzed according to relevant standards and screened to identify compositional ranges corresponding with the relevant compositions of existing grades of steel. To further analyze the effect of copper and phosphorus on the corrosion behavior, dry/wet cyclic corrosion test were performed using plates. A combination of XRD, FTIR, SEM, EDS, and EPMA were used to analyze the corrosion behavior. It was observed that both copper and phosphorus promoted the formation of amorphous substances, supporting the proposed mechanism by previous researchers. Furthermore, in the absence of manganese interference, copper could accumulate at the metal/rust layer interface, rendering the rust layer cation-selective and effectively inhibiting the deep penetration of chloride ions. Moving forward, we expect to develop this high-throughput experiments to investigate the coupling effects of other elements on corrosion behavior.
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