دورية أكاديمية
Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
| العنوان: | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
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| المؤلفون: | Linyu Jin, Xuejun Liu |
| المصدر: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m901-m901 (2009) |
| بيانات النشر: | International Union of Crystallography, 2009. |
| سنة النشر: | 2009 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | Crystallography, QD901-999 |
| الوصف: | In the title compound, [Mn(C7H5O3)2(C14H12N2)(H2O)]·C14H12N2·H2O, the MnII ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxybenzoate anions (3-HBA) and one water molecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water molecule cocrystallized with each complex molecule. Intra- and intermolecular O—H...N and O—H...O hydrogen bonds are also present between the coordinated 3-HBA and water molecules and the uncoordinated dmphen and water molecules in the crystal. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with a centroid–centroid separation of 3.705 (3) Å. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 16005368 1600-5368 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536809025926; https://doaj.org/toc/1600-5368 |
| DOI: | 10.1107/S1600536809025926 |
| URL الوصول: | https://doaj.org/article/2392cfa3301647f187390b5addea4019 |
| رقم الأكسشن: | edsdoj.2392cfa3301647f187390b5addea4019 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536809025926 |