دورية أكاديمية
Recent progress on catalyst development for ring-opening C-O hydrogenolysis of cyclic ethers in the production of biomass-derived chemicals
| العنوان: | Recent progress on catalyst development for ring-opening C-O hydrogenolysis of cyclic ethers in the production of biomass-derived chemicals |
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| المؤلفون: | Keiichi Tomishige, Masayoshi Honda, Hiroshi Sugimoto, Lujie Liu, Mizuho Yabushita, Yoshinao Nakagawa |
| المصدر: | Carbon Neutrality, Vol 3, Iss 1, Pp 1-41 (2024) |
| بيانات النشر: | Springer, 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Renewable energy sources |
| مصطلحات موضوعية: | Furfural, 5-Hydroxymethylfurfural, Hydrogenolysis, Polyester, Polycarbonate, Energy industries. Energy policy. Fuel trade, HD9502-9502.5, Renewable energy sources, TJ807-830 |
| الوصف: | Abstract Catalytic hydrogenolysis systems of C-O bonds in furan ring, tetrahydrofuran ring and tetrahydropyran ring in biomass-derived cyclic compounds are reviewed. Furfural or its hydrogenation products (furfuryl alcohol and tetrahydrofurfuryl alcohol) have been frequently used as substrates for this type of reactions. Ring-opening of furfuryl alcohol over metal catalysts combined with basic components gives a mixture of 1,2-pentanediol, 1,5-pentanediol and other by-products. The selectivity much depends on catalysts and reaction conditions, and good 1,2-pentanediol selectivity can be obtained. For 1,5-pentanediol synthesis, more selective approaches have been reported such as Cu-zeolite catalysts for furfuryl alcohol hydrogenolysis in flow reactor and M-M’Ox-type (M: noble metal; M’: transition metal) supported catalysts or Ni-LnOx (Ln: rare earth element) catalysts for tetrahydrofurfuryl alcohol hydrogenolysis. The metal catalysts and M-M’Ox-type catalysts can be applied to ring-opening hydrogenolysis of other furan- and tetrahydrofuran-based compounds, respectively. Among the products of ring-opening hydrogenolysis of biomass-derived compounds, 1,5-pentanediol seems to be the most important because of the potential use as a monomer. The recent progress and reported properties of polymers using 1,5-pentanediol as a monomer are also summarized. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2788-8614 2731-3948 |
| Relation: | https://doaj.org/toc/2788-8614; https://doaj.org/toc/2731-3948 |
| DOI: | 10.1007/s43979-024-00090-y |
| URL الوصول: | https://doaj.org/article/2402c4e8627a4df9812e5fa872dbdc83 |
| رقم الأكسشن: | edsdoj.2402c4e8627a4df9812e5fa872dbdc83 |
| قاعدة البيانات: | Directory of Open Access Journals |
Find this article in full text from Springer Verlag. 
Full Text Finder | تدمد: | 27888614 27313948 |
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| DOI: | 10.1007/s43979-024-00090-y |