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Evolution of Pauson-Khand Reaction: Strategic Applications in Total Syntheses of Architecturally Complex Natural Products (2016–2020)

التفاصيل البيبلوغرافية
العنوان: Evolution of Pauson-Khand Reaction: Strategic Applications in Total Syntheses of Architecturally Complex Natural Products (2016–2020)
المؤلفون: Sijia Chen, Chongguo Jiang, Nan Zheng, Zhen Yang, Lili Shi
المصدر: Catalysts, Vol 10, Iss 10, p 1199 (2020)
بيانات النشر: MDPI AG, 2020.
سنة النشر: 2020
المجموعة: LCC:Chemical technology
LCC:Chemistry
مصطلحات موضوعية: metal-mediated reactions, Pauson-Khand reaction, cyclopentenones, natural products total syntheses, Chemical technology, TP1-1185, Chemistry, QD1-999
الوصف: Metal-mediated cyclizations are important transformations in a natural product total synthesis. The Pauson-Khand reaction, particularly powerful for establishing cyclopentenone-containing structures, is distinguished as one of the most attractive annulation processes routinely employed in synthesis campaigns. This review covers Co, Rh, and Pd catalyzed Pauson-Khand reaction and summarizes its strategic applications in total syntheses of structurally complex natural products in the last five years. Additionally, the hetero-Pauson-Khand reaction in the synthesis of heterocycles will also be discussed. Focusing on the panorama of organic synthesis, this review highlights the strategically developed Pauson-Khand reaction in fulfilling total synthetic tasks and its synthetic attractiveness is aimed to be illustrated.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2073-4344
Relation: https://www.mdpi.com/2073-4344/10/10/1199; https://doaj.org/toc/2073-4344
DOI: 10.3390/catal10101199
URL الوصول: https://doaj.org/article/26729ae73c2446c4822f274cc71e7547
رقم الأكسشن: edsdoj.26729ae73c2446c4822f274cc71e7547
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:20734344
DOI:10.3390/catal10101199