دورية أكاديمية
Evolution of Pauson-Khand Reaction: Strategic Applications in Total Syntheses of Architecturally Complex Natural Products (2016–2020)
العنوان: | Evolution of Pauson-Khand Reaction: Strategic Applications in Total Syntheses of Architecturally Complex Natural Products (2016–2020) |
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المؤلفون: | Sijia Chen, Chongguo Jiang, Nan Zheng, Zhen Yang, Lili Shi |
المصدر: | Catalysts, Vol 10, Iss 10, p 1199 (2020) |
بيانات النشر: | MDPI AG, 2020. |
سنة النشر: | 2020 |
المجموعة: | LCC:Chemical technology LCC:Chemistry |
مصطلحات موضوعية: | metal-mediated reactions, Pauson-Khand reaction, cyclopentenones, natural products total syntheses, Chemical technology, TP1-1185, Chemistry, QD1-999 |
الوصف: | Metal-mediated cyclizations are important transformations in a natural product total synthesis. The Pauson-Khand reaction, particularly powerful for establishing cyclopentenone-containing structures, is distinguished as one of the most attractive annulation processes routinely employed in synthesis campaigns. This review covers Co, Rh, and Pd catalyzed Pauson-Khand reaction and summarizes its strategic applications in total syntheses of structurally complex natural products in the last five years. Additionally, the hetero-Pauson-Khand reaction in the synthesis of heterocycles will also be discussed. Focusing on the panorama of organic synthesis, this review highlights the strategically developed Pauson-Khand reaction in fulfilling total synthetic tasks and its synthetic attractiveness is aimed to be illustrated. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2073-4344 |
Relation: | https://www.mdpi.com/2073-4344/10/10/1199; https://doaj.org/toc/2073-4344 |
DOI: | 10.3390/catal10101199 |
URL الوصول: | https://doaj.org/article/26729ae73c2446c4822f274cc71e7547 |
رقم الأكسشن: | edsdoj.26729ae73c2446c4822f274cc71e7547 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 20734344 |
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DOI: | 10.3390/catal10101199 |