دورية أكاديمية
Copper-catalyzed N-arylation of amines with aryliodonium ylides in water
العنوان: | Copper-catalyzed N-arylation of amines with aryliodonium ylides in water |
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المؤلفون: | Kasturi U. Nabar, Bhalchandra M. Bhanage, Sudam G. Dawande |
المصدر: | Beilstein Journal of Organic Chemistry, Vol 19, Iss 1, Pp 1008-1014 (2023) |
بيانات النشر: | Beilstein-Institut, 2023. |
سنة النشر: | 2023 |
المجموعة: | LCC:Science LCC:Organic chemistry |
مصطلحات موضوعية: | amines, arylation, c–n bond formation, iodonium ylide, sustainable, Science, Organic chemistry, QD241-441 |
الوصف: | Copper sulfate catalyzed an efficient, inexpensive, and environment-friendly protocol that has been developed for N-arylation of amines with 1,3-cyclohexadione-derived aryliodonium ylides in water as a green solvent. Aromatic primary amines substituted with electron-donating as well as electron-withdrawing groups on the aryl ring reacted smoothly with iodonium ylides to give the corresponding diarylamines with good to excellent yields. Also, secondary amines underwent N-arylation to deliver tertiary amines with moderate yields. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 1860-5397 |
Relation: | https://doaj.org/toc/1860-5397 |
DOI: | 10.3762/bjoc.19.76 |
URL الوصول: | https://doaj.org/article/2e40ef77869a4b7fada128fcc5c13262 |
رقم الأكسشن: | edsdoj.2e40ef77869a4b7fada128fcc5c13262 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 18605397 |
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DOI: | 10.3762/bjoc.19.76 |