دورية أكاديمية
Desenvolvimento de métodos analíticos para determinação de agrotóxicos em sedimentos por cromatografia gasosa monodimensional e bidimensional abrangente com micro detector de captura de elétrons Development of analytical methods for pesticides in sediments by monodimensional and comprehensive two-dimensional gas chromatography with micro electron-capture detection
| العنوان: | Desenvolvimento de métodos analíticos para determinação de agrotóxicos em sedimentos por cromatografia gasosa monodimensional e bidimensional abrangente com micro detector de captura de elétrons Development of analytical methods for pesticides in sediments by monodimensional and comprehensive two-dimensional gas chromatography with micro electron-capture detection |
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| المؤلفون: | Juliana Macedo da Silva, Cláudia Alcaraz Zini, Elina Bastos Caramão, Ewelin Monica Paturi Navarro Canizares, Karen Alam Leal |
| المصدر: | Química Nova, Vol 33, Iss 3, Pp 591-597 (2010) |
| بيانات النشر: | Sociedade Brasileira de Química, 2010. |
| سنة النشر: | 2010 |
| المجموعة: | LCC:Chemistry |
| مصطلحات موضوعية: | pesticides, GCxGC, µECD, Chemistry, QD1-999 |
| الوصف: | The development of analytical methods for determination of eight pesticides of different chemical classes (trichlorfon, propanil, fipronil, propiconazole, trifloxystrobin, permethrin, difenoconazole and azoxystrobin) in sediments with gas chromatography-micro-electron capture detector (GC/µECD) and comprehensive two-dimensional gas chromatography with micro-electron capture detector (GCxGC/µECD) is described. These methods were applied to real sediment samples, and the best results were obtained using a 5% diphenyl-methylpolysiloxane column for 1D-GC. For GCxGC the same column was employed in the first dimension and a 50%-phenyl-methylpolysiloxane stationary phase was placed in the second dimension. Due to the superior peak capacity and selectivity of GCxGC, interfering matrix peaks were separated from analytes, showing a better performance of GCxGC. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English Spanish; Castilian Portuguese |
| تدمد: | 0100-4042 1678-7064 |
| Relation: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000300020; https://doaj.org/toc/0100-4042; https://doaj.org/toc/1678-7064 |
| DOI: | 10.1590/S0100-40422010000300020 |
| URL الوصول: | https://doaj.org/article/e3414e5c2f114fe1a248aa9e491377c7 |
| رقم الأكسشن: | edsdoj.3414e5c2f114fe1a248aa9e491377c7 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 01004042 16787064 |
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| DOI: | 10.1590/S0100-40422010000300020 |