دورية أكاديمية
Pt Electrocatalyst Prepared by Hydrothermal Reduction onto the Gas Diffusion Layer for High-Temperature Formic Acid and Ethanol Fuel PEMFC
| العنوان: | Pt Electrocatalyst Prepared by Hydrothermal Reduction onto the Gas Diffusion Layer for High-Temperature Formic Acid and Ethanol Fuel PEMFC |
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| المؤلفون: | Rayane da Silva Cardoso, Bruna Sartório de Castro, Sophya de Andrade Dias, Maria Clara H. Clemente, Sílvia C. L. Dias, José A. Dias, Rudy Crisafulli, José J. Linares, Gesley A. Veloso Martins |
| المصدر: | Catalysts, Vol 11, Iss 10, p 1246 (2021) |
| بيانات النشر: | MDPI AG, 2021. |
| سنة النشر: | 2021 |
| المجموعة: | LCC:Chemical technology LCC:Chemistry |
| مصطلحات موضوعية: | electrocatalysts, direct deposition, platinum, high temperature PEMFC, hydrogen, ethanol, Chemical technology, TP1-1185, Chemistry, QD1-999 |
| الوصف: | An alternative method for the preparation of PEMFC electrodes is presented in this work based on the direct deposition of Pt particles onto the gas diffusion layer (Pt@GDL) by hydrothermal reduction of the H2PtCl6 precursor from formic acid, ethylene glycol, and ethanol reductive solutions. There is a successful anchorage of Pt particles via the formation of Pt crystal aggregates. The influence of the reducing agent concentration and temperature was studied to analyze their influence on the size, morphology, and distribution of the Pt particles on the gas GDL. The prepared Pt@GDL was tested for formic acid and ethanol high-temperature H3PO4-doped PEMFC. The Pt@GDL prepared in the formic acid reductive atmosphere presented the best performance associated with the formation of smaller Pt crystals and a more homogeneous dispersion of the Pt particles. For formic acid and ethanol-fed high-temperature PEMFC using a H3PO4-doped polybenzimidazole membrane as the solid electrolyte, maximum power densities of 0.025 and 0.007 W cm−2 were drawn at 200 °C, respectively. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2073-4344 |
| Relation: | https://www.mdpi.com/2073-4344/11/10/1246; https://doaj.org/toc/2073-4344 |
| DOI: | 10.3390/catal11101246 |
| URL الوصول: | https://doaj.org/article/e3ebd0b50e90411e9e793b6af2e3d2bb |
| رقم الأكسشن: | edsdoj.3ebd0b50e90411e9e793b6af2e3d2bb |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20734344 |
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| DOI: | 10.3390/catal11101246 |