دورية أكاديمية
The charge-assisted hydrogen-bonded organic framework (CAHOF) self-assembled from the conjugated acid of tetrakis(4-aminophenyl)methane and 2,6-naphthalenedisulfonate as a new class of recyclable Brønsted acid catalysts
| العنوان: | The charge-assisted hydrogen-bonded organic framework (CAHOF) self-assembled from the conjugated acid of tetrakis(4-aminophenyl)methane and 2,6-naphthalenedisulfonate as a new class of recyclable Brønsted acid catalysts |
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| المؤلفون: | Svetlana A. Kuznetsova, Alexander S. Gak, Yulia V. Nelyubina, Vladimir A. Larionov, Han Li, Michael North, Vladimir P. Zhereb, Alexander F. Smol'yakov, Artem O. Dmitrienko, Michael G. Medvedev, Igor S. Gerasimov, Ashot S. Saghyan, Yuri N. Belokon |
| المصدر: | Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 1124-1134 (2020) |
| بيانات النشر: | Beilstein-Institut, 2020. |
| سنة النشر: | 2020 |
| المجموعة: | LCC:Science LCC:Organic chemistry |
| مصطلحات موضوعية: | brønsted acid catalyst, charge-assisted hydrogen-bonded framework, diels–alder, epoxide ring opening, heterogeneous catalyst, Science, Organic chemistry, QD241-441 |
| الوصف: | The acid–base neutralization reaction of commercially available disodium 2,6-naphthalenedisulfonate (NDS, 2 equivalents) and the tetrahydrochloride salt of tetrakis(4-aminophenyl)methane (TAPM, 1 equivalent) in water gave a novel three-dimensional charge-assisted hydrogen-bonded framework (CAHOF, F-1). The framework F-1 was characterized by X-ray diffraction, TGA, elemental analysis, and 1H NMR spectroscopy. The framework was supported by hydrogen bonds between the sulfonate anions and the ammonium cations of NDS and protonated TAPM moieties, respectively. The CAHOF material functioned as a new type of catalytically active Brønsted acid in a series of reactions, including the ring opening of epoxides by water and alcohols. A Diels–Alder reaction between cyclopentadiene and methyl vinyl ketone was also catalyzed by F-1 in heptane. Depending on the polarity of the solvent mixture, the CAHOF F-1 could function as a purely heterogeneous catalyst or partly dissociate, providing some dissolved F-1 as the real catalyst. In all cases, the catalyst could easily be recovered and recycled. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1860-5397 70546169 |
| Relation: | https://doaj.org/toc/1860-5397 |
| DOI: | 10.3762/bjoc.16.99 |
| URL الوصول: | https://doaj.org/article/e447d70dd70546169bf17037a67acf93 |
| رقم الأكسشن: | edsdoj.447d70dd70546169bf17037a67acf93 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 18605397 70546169 |
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| DOI: | 10.3762/bjoc.16.99 |