دورية أكاديمية
Molecular Structure Modulated Trap Distribution and Carrier Migration in Fluorinated Epoxy Resin
| العنوان: | Molecular Structure Modulated Trap Distribution and Carrier Migration in Fluorinated Epoxy Resin |
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| المؤلفون: | Jin Li, Yufan Wang, Zhaoyu Ran, Hang Yao, Boxue Du, Tatsuo Takada |
| المصدر: | Molecules, Vol 25, Iss 13, p 3071 (2020) |
| بيانات النشر: | MDPI AG, 2020. |
| سنة النشر: | 2020 |
| المجموعة: | LCC:Organic chemistry |
| مصطلحات موضوعية: | epoxy resin, surface charge, molecular structure, trap distribution, quantum chemical calculation, Organic chemistry, QD241-441 |
| الوصف: | Surface charge accumulation on epoxy insulators is one of the most serious problems threatening the operation safety of the direct current gas-insulated transmission line (GIL), and can be efficiently inhibited by the surface modification technology. This paper investigated the mechanisms of fluorination modulated surface charge behaviors of epoxy resin through quantum chemical calculation (QCC) analysis of the molecular structure. The results show that after fluorination, the surface charge dissipation process of the epoxy sample is accelerated by the introduced shallow trap sites, which is further clarified by the carrier mobility model. The electron distribution probability of the highest occupied molecular orbitals (HOMO) under positive charging and the lowest unoccupied molecular orbitals (LUMO) under negative charging shows distinctive patterns. It is illustrated that electrons are likely to aggregate locally around benzenes for the positively charged molecular structure, while electrons tend to distribute all along the epoxy chain under negatively charging. The calculated results verify that fluorination can modulate surface charge behaviors of epoxy resin through redesigning its molecular structure, trap distribution and charging patterns. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 25133071 1420-3049 |
| Relation: | https://www.mdpi.com/1420-3049/25/13/3071; https://doaj.org/toc/1420-3049 |
| DOI: | 10.3390/molecules25133071 |
| URL الوصول: | https://doaj.org/article/ea4738ada3424a639424a223e3459bd6 |
| رقم الأكسشن: | edsdoj.4738ada3424a639424a223e3459bd6 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 25133071 14203049 |
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| DOI: | 10.3390/molecules25133071 |