دورية أكاديمية
Dibromido(4′-phenyl-2,2′:6′,2′′-terpyridyl)copper(II) hemihydrate
العنوان: | Dibromido(4′-phenyl-2,2′:6′,2′′-terpyridyl)copper(II) hemihydrate |
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المؤلفون: | Zhen Ma, Chunyan Bi, Guangyou Ran, Zhang Wu, Baoqing Liu, Miao Hu, Yanpeng Xing |
المصدر: | Acta Crystallographica Section E, Vol 66, Iss 4, Pp m465-m465 (2010) |
بيانات النشر: | International Union of Crystallography, 2010. |
سنة النشر: | 2010 |
المجموعة: | LCC:Crystallography |
مصطلحات موضوعية: | Crystallography, QD901-999 |
الوصف: | The title CuII complex, [CuBr2(C21H15N3)]·0.5H2O, was obtained by the hydrothermal reaction of copper(II) bromide, 4′-phenyl-2,2′:6′,2′′-terpyridyl (4′-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex molecules and a water molecule in the asymmetric unit. The CuII cation is ligated by three N atoms of L and two bromide anions, forming an irregular CuN3Br2 polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O—H...Br hydrogen bonds link the molecules in a three-dimensional network. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 16005368 1600-5368 |
Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536810010585; https://doaj.org/toc/1600-5368 |
DOI: | 10.1107/S1600536810010585 |
URL الوصول: | https://doaj.org/article/48e87c23829f4a88b2286699fcbcaf0a |
رقم الأكسشن: | edsdoj.48e87c23829f4a88b2286699fcbcaf0a |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 16005368 |
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DOI: | 10.1107/S1600536810010585 |