دورية أكاديمية
Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
| العنوان: | Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] |
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| المؤلفون: | Covaci Ancuța, Silvestru Cristian, Silvestru Anca |
| المصدر: | Main Group Metal Chemistry, Vol 44, Iss 1, Pp 261-266 (2021) |
| بيانات النشر: | De Gruyter, 2021. |
| سنة النشر: | 2021 |
| المجموعة: | LCC:Chemistry |
| مصطلحات موضوعية: | triarylphosphane ligand, cadmium complexes, chelating behavior, nmr spectroscopy, crystal and molecular structure, Chemistry, QD1-999 |
| الوصف: | The reaction between CdCl2 and PPh2{C6H4 [CH2N(CH2CH2)2O]-2} (1) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] (2). The complex 2 was characterized in solution by NMR spectroscopy (1H, 13C, and 31P). Single-crystal X-ray diffraction studies revealed no intramolecular N→P interaction in 1. The phosphane ligand behaves as a P,N chelating moiety in the cadmium complex 2, thus resulting in a species containing distorted tetrahedral environments around cadmium and phosphorus. Short intermolecular interactions CH‧‧‧π aryl and CH‧‧‧O in 1 and CH‧‧‧π aryl and CH‧‧‧Cl in 2 resulted in supramolecular networks. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 0792-1241 2191-0219 |
| Relation: | https://doaj.org/toc/0792-1241; https://doaj.org/toc/2191-0219 |
| DOI: | 10.1515/mgmc-2021-0029 |
| URL الوصول: | https://doaj.org/article/55a226a6ab9a48bebd9afcac152d2cc9 |
| رقم الأكسشن: | edsdoj.55a226a6ab9a48bebd9afcac152d2cc9 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 07921241 21910219 |
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| DOI: | 10.1515/mgmc-2021-0029 |