دورية أكاديمية
Current State of the Art of the Solid Rh-Based Catalyzed Hydroformylation of Short-Chain Olefins
| العنوان: | Current State of the Art of the Solid Rh-Based Catalyzed Hydroformylation of Short-Chain Olefins |
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| المؤلفون: | Schirin Hanf, Luis Alvarado Rupflin, Roger Gläser, Stephan Andreas Schunk |
| المصدر: | Catalysts, Vol 10, Iss 5, p 510 (2020) |
| بيانات النشر: | MDPI AG, 2020. |
| سنة النشر: | 2020 |
| المجموعة: | LCC:Chemical technology LCC:Chemistry |
| مصطلحات موضوعية: | heterogeneous catalysis, hydroformylation, short-chain olefins, heterogenized rhodium catalysts, Chemical technology, TP1-1185, Chemistry, QD1-999 |
| الوصف: | The hydroformylation of olefins is one of the most important homogeneously catalyzed processes in industry to produce bulk chemicals. Despite the high catalytic activities and selectivity’s using rhodium-based homogeneous hydroformylation catalysts, catalyst recovery and recycling from the reaction mixture remain a challenging topic on a process level. Therefore, technical solutions involving alternate approaches with heterogeneous catalysts for the conversion of olefins into aldehydes have been considered and research activities have addressed the synthesis and development of heterogeneous rhodium-based hydroformylation catalysts. Different strategies were pursued by different groups of authors, such as the deposition of molecular rhodium complexes, metallic rhodium nanoparticles and single-atom catalysts on a solid support as well as rhodium complexes present in supported liquids. An overview of the recent developments made in the area of the heterogenization of homogeneous rhodium catalysts and their application in the hydroformylation of short-chain olefins is given. A special focus is laid on the mechanistic understanding of the heterogeneously catalyzed reactions at a molecular level in order to provide a guide for the future design of rhodium-based heterogeneous hydroformylation catalysts. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2073-4344 |
| Relation: | https://www.mdpi.com/2073-4344/10/5/510; https://doaj.org/toc/2073-4344 |
| DOI: | 10.3390/catal10050510 |
| URL الوصول: | https://doaj.org/article/5fb8cda4f47c45d9ba464d737dcef9d8 |
| رقم الأكسشن: | edsdoj.5fb8cda4f47c45d9ba464d737dcef9d8 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 20734344 |
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| DOI: | 10.3390/catal10050510 |