دورية أكاديمية
Crystal structure of 2-{[2-(3-phenylallylidene)hydrazin-1-yl]thiocarbonylsulfanylmethyl}pyridinium chloride
| العنوان: | Crystal structure of 2-{[2-(3-phenylallylidene)hydrazin-1-yl]thiocarbonylsulfanylmethyl}pyridinium chloride |
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| المؤلفون: | May Lee Low, Thahira Begum S. A. Ravoof, Mohamed Ibrahim Mohamed Tahir, Karen A. Crouse, Edward R. T. Tiekink |
| المصدر: | Acta Crystallographica Section E, Vol 70, Iss 11, Pp o1207-o1208 (2014) |
| بيانات النشر: | International Union of Crystallography, 2014. |
| سنة النشر: | 2014 |
| المجموعة: | LCC:Crystallography |
| مصطلحات موضوعية: | crystal structure, hydrogen bonding, S-substituted dithiocarbazates, salt, Crystallography, QD901-999 |
| الوصف: | In the title salt of an S-substituted dithiocarbazate, C16H16N3S2+·Cl−, the dihedral angles between the almost planar (r.m.s deviation = 0.005 Å) central CN2S2 residue and the terminal pyridinium and phenyl rings are 80.09 (11) and 3.82 (11)°, respectively, indicating the cation has an L-shape; the amine H and thione S atoms are syn. The conformation about each of the imine [1.376 (3) Å] and ethene [1.333 (4) Å] bonds is E. The shortened C—C bond [1.444 (4) Å] linking the double bonds is consistent with conjugation in this part of the molecule. In the crystal, supramolecular layers with a jagged topology are formed by charged-assisted amine-H...Cl− and pyridinium-N+—H...Cl− hydrogen bonds. The layers stack along the a axis with no specific directional interactions between them. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1600-5368 16005368 |
| Relation: | http://scripts.iucr.org/cgi-bin/paper?S1600536814023228; https://doaj.org/toc/1600-5368 |
| DOI: | 10.1107/S1600536814023228 |
| URL الوصول: | https://doaj.org/article/d66be8cedec24a50b2d7a3cc0949c493 |
| رقم الأكسشن: | edsdoj.66be8cedec24a50b2d7a3cc0949c493 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16005368 |
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| DOI: | 10.1107/S1600536814023228 |