دورية أكاديمية

Exciton States in Monolayer MoSe_{2} and MoTe_{2} Probed by Upconversion Spectroscopy

التفاصيل البيبلوغرافية
العنوان: Exciton States in Monolayer MoSe_{2} and MoTe_{2} Probed by Upconversion Spectroscopy
المؤلفون: B. Han, C. Robert, E. Courtade, M. Manca, S. Shree, T. Amand, P. Renucci, T. Taniguchi, K. Watanabe, X. Marie, L. E. Golub, M. M. Glazov, B. Urbaszek
المصدر: Physical Review X, Vol 8, Iss 3, p 031073 (2018)
بيانات النشر: American Physical Society, 2018.
سنة النشر: 2018
المجموعة: LCC:Physics
مصطلحات موضوعية: Physics, QC1-999
الوصف: Transitions metal dichalcogenides (TMDs) are direct gap semiconductors in the monolayer (ML) limit with fascinating optical and spin-valley properties. The strong optical absorption of up to 20% for a single ML is governed by excitons, electron-hole pairs bound by Coulomb attraction. Excited exciton states in MoSe_{2} and MoTe_{2} monolayers have so far been elusive because of their low oscillator strength and strong inhomogeneous broadening. Here, we show that encapsulation in hexagonal boron nitride results in an emission line width of the A:1s exciton below 1.5 meV and 3 meV in our MoSe_{2} and MoTe_{2} monolayer samples, respectively. This allows us to investigate the excited exciton states by photoluminescence upconversion spectroscopy for both monolayer materials. The excitation laser is tuned into resonance with the A:1s transition, and we observe emission of excited exciton states up to 200 meV above the laser energy. We demonstrate bias control of the efficiency of this nonlinear optical process. We discuss the origin of the upconversion effect. Our model calculations suggest an exciton-exciton (Auger) scattering mechanism specific to TMD MLs involving an excited conduction band, thus generating high-energy excitons with small wave vectors. The optical transitions are further investigated by white light reflectivity, photoluminescence excitation, and resonant Raman scattering, confirming their origin as excited excitonic states in monolayer thin semiconductors.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 2160-3308
Relation: https://doaj.org/toc/2160-3308
DOI: 10.1103/PhysRevX.8.031073
URL الوصول: https://doaj.org/article/e6d6768ebb51411fa7326f9fb3005938
رقم الأكسشن: edsdoj.6d6768ebb51411fa7326f9fb3005938
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:21603308
DOI:10.1103/PhysRevX.8.031073