دورية أكاديمية
Modeling and simulation of the desulfurization of a sour gas streams by adsorption: Influence of the isotherm model
| العنوان: | Modeling and simulation of the desulfurization of a sour gas streams by adsorption: Influence of the isotherm model |
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| المؤلفون: | dos Santos João Paulo Lobo, de Lima Cunha Acto, de Lobato Ana Katerine Carvalho Lima, Moraes Caetano, Baptista Severo João Júnior, dos Santos Luiz Carlos Lobato |
| المصدر: | Chemical Industry and Chemical Engineering Quarterly, Vol 25, Iss 1, Pp 77-87 (2019) |
| بيانات النشر: | Association of the Chemical Engineers of Serbia, 2019. |
| سنة النشر: | 2019 |
| المجموعة: | LCC:Chemical engineering |
| مصطلحات موضوعية: | natural gas, elementar sulfur, desulfurization methods, adsorption, CFD simulation, Chemical engineering, TP155-156, Chemical industries, HD9650-9663 |
| الوصف: | The presence of elemental sulfur (S8) in natural gas streams has caused several problems at the delivery points, one of the most recurrent being the deposit of "yellow powder" in the pilots of pressure control valves. The presence of H2S in the natural gas stream may serve as the source for the S8 and/or increase the solubility thereof in the gas. Studies have shown that adsorption control mechanisms are more attractive for use in pipelines to control S8 deposition. In this study, computational simulations were performed in the software COMSOL Multiphysics, using the computational fluid dynamics (CFD) technique and 13X zeolite as adsorbent. The isotherm models of Langmuir, BET, Freundlich, Toth and Sips were tested in the modeling and simulation and the results obtained showed that the isotherm models presented the following decreasing order of precision in relation to the experimental results: Sips = = Freundlich > Toth > Langmuir > BET. In addition, it was possible to verify that the variation of the coefficient of axial dispersion significantly influences the size of the mass transfer zone. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1451-9372 2217-7434 |
| Relation: | https://doaj.org/toc/1451-9372; https://doaj.org/toc/2217-7434 |
| DOI: | 10.2298/CICEQ180202020S |
| URL الوصول: | https://doaj.org/article/72000e73c5a04fe48f0a4c5acff75122 |
| رقم الأكسشن: | edsdoj.72000e73c5a04fe48f0a4c5acff75122 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14519372 22177434 |
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| DOI: | 10.2298/CICEQ180202020S |