دورية أكاديمية
Crystal structure of tetrakis(μ-2-hydroxy-3,5-diisopropylbenzoato)bis[(dimethyl sulfoxide)copper(II)]
العنوان: | Crystal structure of tetrakis(μ-2-hydroxy-3,5-diisopropylbenzoato)bis[(dimethyl sulfoxide)copper(II)] |
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المؤلفون: | Daniel G. Shlian, Rachael H. Summers, Katelyn Martinez, Rita K. Upmacis |
المصدر: | Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 3, Pp 335-338 (2024) |
بيانات النشر: | International Union of Crystallography, 2024. |
سنة النشر: | 2024 |
المجموعة: | LCC:Crystallography |
مصطلحات موضوعية: | crystal structure, binuclear copper, 3,5-diisopropylsalicylate, dimethyl sulfoxide., Crystallography, QD901-999 |
الوصف: | Metal complexes of 3,5-diisopropylsalicylate are reported to have anti-inflammatory and anti-convulsant activities. The title binuclear copper complex, [Cu2(C13H17O3)4(C2H6OS)2] or [Cu(II)2(3,5-DIPS)4(DMSO)2], contains two five-coordinate copper atoms that are bridged by four 3,5-diisopropylsalicylate ligands and capped by two axial dimethyl sulfoxide (DMSO) moieties. Each copper atom is attached to four oxygen atoms in an almost square-planar fashion, with the addition of a DMSO ligand in an apical position leading to a square-pyramidal arrangement. The hydroxy group of the diisopropylsalicylate ligands participates in intramolecular O—H...O hydrogen-bonding interactions. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2056-9890 20569890 |
Relation: | http://scripts.iucr.org/cgi-bin/paper?S205698902400166X; https://doaj.org/toc/2056-9890 |
DOI: | 10.1107/S205698902400166X |
URL الوصول: | https://doaj.org/article/75cf7790d5e04d95ac1bd83b777687c8 |
رقم الأكسشن: | edsdoj.75cf7790d5e04d95ac1bd83b777687c8 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 20569890 |
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DOI: | 10.1107/S205698902400166X |