Explosions of hybrid mixtures are an interesting theoretical and experimental problem in explosion sciences, because they combine the physicochemical properties of flammable gases and dusts. A hybrid mixture is composed of at least two substances in two or more states. The influence of the common presence of flammable gas on the explosiveness parameters of the combustible dust itself is proven. In this study, we present the effect of higher initiation temperatures, different initial sources of initiation with different energies, and the effect of the volume of explosion chambers on the explosions of hybrid mixtures arising from the use of alternative energy sources. The experiments were carried out in 20 L and 1.00 m3 explosion chambers (according to EN 14034-1+A1:2011–EN 14034-4+A1:2011). The accredited method of the Energy Research Centre, VSB-TU Ostrava, for tests was used. The goal is to approximate the behaviour of these systems under different initiation conditions so that it is possible to avoid excessively conservative or overly optimistic results, which then affect the determination of explosion parameters for practical use. It was found that the volume of the explosion chambers in combination with the used initiation source has a fundamental influence on the course of the explosion characteristics.
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