In this paper, we focus on the strong product of the pentagonal networks. Let $ R_{n} $ be a hexagonal network composed of $ 2n $ pentagons and $ n $ quadrilaterals. Let $ P_{n}^{2} $ denote the graph formed by the strong product of $ R_{n} $ and its copy $ R_{n}^{\prime} $. By utilizing the decomposition theorem of the normalized Laplacian characteristics polynomial, we characterize the explicit formula of the multiplicative degree-Kirchhoff index completely. Moreover, the complexity of $ P_{n}^{2} $ is determined.
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