دورية أكاديمية
Redox‐Driven Cu─Pd Bond Formation to Enhance the Efficiency for Electroreduction of CO2 to CO
| العنوان: | Redox‐Driven Cu─Pd Bond Formation to Enhance the Efficiency for Electroreduction of CO2 to CO |
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| المؤلفون: | Yi-An Lai, You-Chiuan Chu, Chia-Jui Chang, Kuan-Hsu Chen, Yu-Cheng Hsiao, Chun-Chih Chang, Mei-Yi Liao, Hao Ming Chen |
| المصدر: | Advanced Energy & Sustainability Research, Vol 3, Iss 10, Pp n/a-n/a (2022) |
| بيانات النشر: | Wiley-VCH, 2022. |
| سنة النشر: | 2022 |
| المجموعة: | LCC:Environmental technology. Sanitary engineering LCC:Renewable energy sources |
| مصطلحات موضوعية: | bimetallic catalysts, CO2 electrochemical reductions, dynamic structures, in situ X-ray absorption spectroscopy, Environmental technology. Sanitary engineering, TD1-1066, Renewable energy sources, TJ807-830 |
| الوصف: | The redox reaction as the driving force induces the dynamic structure of the electrocatalyst, which enhances the performance of the catalysis. Yet, it lacks the understanding of the influence of redox driving force on the transforming process, inhibiting obtaining the actual factor that determines the catalytic performance. Resorting to the pulse and in situ methodology, herein, the effect of spontaneous reoxidation on the structural transformation of the Cu–Pd bimetallic catalyst for CO2 electroreduction is investigated. During the pulse program, applying the open‐circuit voltage and cathodic potential intermittently oxidizes and reduces the Cu–Pd bimetallic catalyst, which systematically reveals the catalyst redox reaction imparting the increase in CO2‐to‐CO selectivity. Through in situ X‐ray absorption spectroscopy (XAS), the dynamic structure induced by the spontaneous reoxidation is unveiled, suggesting the Cu─Pd bond formation for the bimetallic catalyst with a higher Pd content. Such a reoxidation‐induced Cu─Pd bond enhances the CO faradaic efficiency to 88% with the CO current density of −132 mA cm−2. By the methodologies, a new perspective is provided to understand the redox‐driven dynamic structure and the corresponding effect on the product selectivity, which is a vital concept to design the new catalysts in the future. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 2699-9412 |
| Relation: | https://doaj.org/toc/2699-9412 |
| DOI: | 10.1002/aesr.202200075 |
| URL الوصول: | https://doaj.org/article/7a28d7d5f90e43bfb73650ae46e129f5 |
| رقم الأكسشن: | edsdoj.7a28d7d5f90e43bfb73650ae46e129f5 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 26999412 |
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| DOI: | 10.1002/aesr.202200075 |